Organic Chemistry (701)



50 Mcqs Questions for preparation of online exam.
                               

                                   👇


1...Trans - Cyclopropane 1,2 di carboxylic acid is______

👉Optically inactive

👉None of the above

👉Optically active ☑️

👉Meso compound


2...Point group of Bicyclo (2,2,2) Octane is

👉D₃d

👉C₃h

👉D₃h ☑️

👉D₂d


3...The glycosidic bond

👉in maltose is not hydrolyzed in lactose intolerant humans

👉in sucrose is hydrolyzed by bees

👉both (b) and (c) ☑️

👉joins glucose and fructose to form sucrose


4...Arrange the following trans 1,2 Di methyl Cyclohexane conformers in order of its Stability is

👉aa > ee > ea

👉aa > ea > ee

👉ee > aa > ea

👉ee > ea > aa ☑️


5...Which of the following statements is true?

👉Sugar component of a nucleotide is ribose

👉Sugar component of a nucleotide is deoxyribose

👉The bases in nucleotides are attached to a pentose sugar moiety by a glycosidic linkage ☑️

👉The sugar molecule of the nucleotide is in L-configuration


6...An aldo hexose will have _____ stereoisomers

👉16 ☑️

👉2

👉4

👉8


7...Which of the following is not a disaccharide?

👉lactose

👉cellobiose

👉none of these

👉amylose ☑️


8...What is the molecular formula of sucrose?

👉C₁₂H₂₀O₁₁

👉C₁₂H₂₂O₁₁ ☑️

👉C₁₀H₂₀O₁₀

👉C₆H₁₂O₆


9...Which property is found in nucleosides and nucleotides?

👉Both contain an aldose with hydroxyl groups that can tautomerize

👉Both contain an anomeric carbon atom that is part of a β-N-glycosidic bond ☑️

👉Both contain a covalent phosphodister bond that is broken in strong acid

👉Both contain a nitrogenous base, a pentose, and at least one phosphate group 


10...A major component of RNA but not of DNA is:

👉adenine

👉cytosine

👉uracil ☑️

👉guanine


11...How many constitutional isomers are possible for the formula C₆H₁₄?

👉4

👉5 ☑️

👉3

👉2


12...Trans 1,2 di carboxylic acid is more stable than its Cis form Because of

👉Torsional angle 30⁰

👉Torsional angle 60⁰

👉Torsional angle 120⁰ ☑️

👉Torsional angle 90⁰ 


13...Which component is found in both guanosine and uridine?

👉Both contain a pyranose

👉Both contain an aldohexose

👉Both contain a 1-9 - bond.

👉Both contain three hydroxyl groups ☑️


14...Which is a general property of both nucleosides and nucleotides?

👉Both contain a pentose in the form of a furanose ☑️

👉Both contain a hemiacetal or hemiketal bond

👉Both contain at least one 5’-phosphate group

👉Both contain a nitrogenous base that forms covalent H-bonds


15...Which of the following is the highest energy conformation of cyclo hexane?

👉eclipsed 

👉chair ☑️

👉boat

👉half- chair


16...Which conformation of trans- 1 - isopropyl - 3 - methyl cyclohexane would be present in greatest amount at equilibrium?

👉The conformation with both groups equatorial

👉The conformation with both groups axial

👉The conformation with the methyl group axial and the isopropyl group equatorial ☑️

👉The conformation with the methyl group equatorial and the isopropyl group axial


17...Which of the following correctly lists the conformations of cyclo hexane in order of increasing energy?

👉chair < boat < twist < half-chair

👉chair < twist < half-chair < boat

👉chair < twist < boat < half-chair ☑️

👉half-chair < boat < twist < chair


18...The sugar molecule in a nucleotide is

👉Pentose ☑️

👉Hexose

👉Tetrose

👉Triose


19...Building blocks of nucleic acids are

👉Amino acids

👉Histones

👉Nucleotides ☑️

👉Nucleosides


20...Which of the statements below correctly describes the chair conformations of trans- 1, 4-di methyl cyclohexane?

👉The higher energy chair conformation contains one axial methyl group and one equatorial Methyl group

👉The two chair conformations are of equal energy

👉The higher energy chair conformation contains two axial methyl groups

👉The lower energy chair conformation contains one axial methyl group and one equatorial Methyl group ☑️


21...Arrange the following conformers of butane in order of energy, lowest to highest

👉eclipsed< gauche< anti< totally eclipsed

👉gauche<eclipsed<anti<totally eclipsed

👉anti < gauche < eclipsed < totally eclipsed ☑️

👉gauche<anti< totally eclipsed<eclipsed


22...Which structural feature is shared by both uracil and thymine?

👉Both contain three nitrogen atoms

👉Both contain two keto groups ☑️

👉Both contain one methyl group

👉Both contain a five-membered ring


23...How many stereo isomers are present in 2-Hydroxy Methyl 1-cyclopropane Carboxylic acid

👉4 ☑️

👉8

👉16

👉2


24...Glycosidic bond in sucrose is____

👉β 1 – 2

👉α 1 – 4

👉β 1 – 4

👉α 1 – 2 ☑️


25...Which of the following is the most stable conformation of 1-bromo propane?
                              

☑️





















26...The rotation about the (C₂– C₃) carbon-carbon bond of n-butane requires the energy of about

👉30 kJ/mol

👉3 kJ/mol ☑️

👉50 kJ/mol

👉100 kJ/mol


27...The infinity of intermediate conformations are called ___________

👉Staggered conformations

👉Gauche

👉Skew conformations ☑️

👉Eclipsed conformations


28...Which of the following is least stable?

👉Gauche conformation

👉Anti conformation

👉Eclipsed conformation ☑️

👉Staggered conformation


29...2-bromo cyclohexanone is more stable when

👉Br is at axial Posiiton ☑️

👉Br is at equatorial Posiiton

👉Both Positiion


30...Which of the following is an aldotriose?

👉Dihydroxyacetone

👉Ribulose

👉Erythrose

👉Glyceraldehyde ☑️


31...The glycosidic linkage between two glucose molecules in isomaltose is

👉α 1 – 4

👉β 1 – 6

👉α 1 – 6 ☑️

👉β 1 – 4


32...Identify the purine base of nucleic acids in the following

👉Cytosine

👉Thymine

👉Uracil

👉Adenine ☑️


33...12. Select the odd one from the following

👉xylose

👉erythrose ☑️

👉lyxose

👉arabinose


34...The sugar which forms major component of nucleic acids is

👉mannose

👉maltose

👉ribose ☑️

👉galactose


35...Hydrolysis of lactose yields

👉fructose and galactose

👉galactose and glucose ☑️

👉galactose and fructose

👉glucose and fructose


36...Which of the following statements is a correct description of the most stable conformation of 1, 1, 3- tri methyl cyclohexane?

👉The methyl group at C-3 is equatorial ☑️

👉C-1 is a quaternary carbon and C-3 is a secondary carbon

👉C-1 is a tertiary carbon and C-3 is a secondary carbon

👉C-1 is a tertiary carbon and C-3 is a primary carbon


37...Arrangement of nucleotides in DNA can be seen by

👉Light microscope

👉X-Ray crystallography ☑️

👉Electron microscope

👉Ultra centrifuge


38...The compound that consists of ribose linked by an N-glycosidic bond to N-9 of adenine is:

👉a pyrimidine nucleotide

👉deoxyribonucleoside

👉a purine nucleotide

👉adenosine ☑️


39...Which of the following statements is true?

👉Sugar component of a nucleotide is deoxyribose

👉The sugar molecule of the nucleotide is in L-configuration

👉The bases in nucleotides are attached to a pentose sugar moiety by a glycosidic linkage ☑️

👉Sugar component of a nucleotide is ribose


40...Conformations are different arrangements of atoms that can be converted into one another by rotation about

👉Double bond

👉Covalent bond

👉Single bond ☑️

👉Triple bond


41...Which cyclo alkane has the least ring strain

👉Cyclo propane

👉Cyclo hexane ☑️

👉Cyclo butane

👉Cyclo pentane 


42...In the most stable conformation of cis-1,4-dimethyl cyclohexane, the methyl groups are:

👉alternating between being both axial and both equatorial

👉both axial 

👉both equatorial

👉one axial, one equatorial ☑️


43...The energy required to rotate n-butane molecule about the carbon-carbon bond is called

👉Enantiomeric energy

👉Torsional energy ☑️

👉Potential energy 

👉Rotational energy


44...Gauche conformation is less stable due to _______

👉Torsional strain

👉Hydrogen bonding

👉Vander Waal’s repulsion ☑️

👉Covalent bonding


45...Which is the proper chair conformation of menthol?

☑️


46...What is the composition of nucleoside?

👉a base + a sugar + phosphate

👉a sugar + a phosphate

👉a base + a sugar ☑️

👉a base + a phosphate


47...Humans are unable to digest

👉starch

👉complex carbohydrates

👉cellulose ☑️

👉denatured proteins


48...In gauche conformations, the methyl groups are___________

👉180⁰ a part

👉60⁰ a part ☑️

👉360⁰ a part

👉90⁰ a part


49...Which of the following is a keto tetrose?

👉Xylulose

👉Psicose

👉Erythrulose ☑️

👉Sorbose


50...which form is more stable in Cyclohexane -1,4 diol

👉twist

👉Chair

👉Half Chair

👉Boat ☑️

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