701 Materials - M.N science College

 1. In purines which two rings are fused to each other?

a] pyrimidine & imidazole

b] pyrimide & furan

c] pyrene & furan

d] None of these


2. The formation of alloxan from uric acid, this reaction indicates that...

a] imidazole ring present in uric acid

b] pyrrole ring present in uric acid

c] pyrimidine ring present in uric acid

d] None of these


3. name of this compound :(CH3)3CCOOH

A] parabanic acid

b] pivalic acid

c] allantoin

d] alloxan


4. which of this structure is unsymmetrical?

A] Medicus formula of uric acid

b] fitting formula of uric acid 

c] a & b both

d] None of these


5. which sentence is correct in following

A] molecular formula of caffeine C8H10O2N4

 B] three N-CH3 groups present in caffeine 

C] caffeine has uric acid structure

D] All of the above


6. in which compound 3’ or 5’ point of linkage phosphoric acid are present

A] ribose nucleoside

b] deoxyribose nucleoside

c] a and b both 

d] None of these


7. which starch are water-soluble

A] α- amylose

b] amylose pectine

c] a and b both 

d] None of these


8. the oxidation of allantoin with nitric acid which product is obtained

A] parabenic acid

b] hydantoin

c] oxalic acid

d] allaxone


9. how many glycose units present in a chain

A] 300 to 350 units

b] 100 to 150 units

c] 3000 units

d] 1000 units

 

10. nucleoside is made of...

A] nitrogenous base + pentose sugar

b] pentose sugar + phosphoric acid 

C] nitrogenous base + phosphoric acid 

d] none of these


11. conformer of BHC which conformer is optically active

A] β- conformer

b] δ- conformer

c] α- conformer

d] ϒ- conformer


12. conformer of BHC which conformer is most stable

A] β- conformer

b] δ- conformer

c] α- conformer

d] ϒ- conformer


13. which conformer of cyclo hexane is more stable?

A] chair

b] boat

c] twist boat

d] none of these


14. which system is present in camphor?

A] bicyclo (2,2,1) heptane

b] bicyclo (2,2,1) octane

c] bicyclo (2,1,1) hexane 

d] bicyclo (1,1,1) pentane


15. in cyclopropane stablility of trans isomer is than cis isomer.

A] higher

b] lower

c] same

d] neglatable


16. in cyclohexan 1,4 diol...........

A] boat form is more stable than chair form

b] chair form is more stable than boat form 

c] both are equally stable

d] None of these


17. in 2 Bromo cyclo hexanone why the equatorial form is less stable than axial form? 

A] dipole-dipole interaction

B] 1,3 diarial interaction 

C] H- bonding

D] A & C both


18. in alcohol & ether which type of isomerism is present

A] metamerism

b] chain

c] functional

d] position


19. which point group present in bicyclo (2,2,2) octane? 

A] D3h   b] C3v

c] C2v d] D2h

 

20. which conformer of BHC contain insectiside properties 

A] α b] ɺ c] Ѵ d] ɳ


21. oestrone is ............

A] steroid b] non--- steroid

c] both d] None of these


22. in which compound two ketonic group is present

A] progesterone b] oesterone

c] lanosterol d] ergosterol


23. M.F. of ergosterol ..........

A] C28 H44 O B] C18H22O

C] C21H30O D] C30H50O


24. in which compound geminal dimethyl group is present?

A] lanosterol b] oestrone

c] progesteroned] None of these


25. the source of hormone is

A] corpus luteum

b] placenta pregnancy urine 

c] adrenal cortex

d] all of these


26. acetylation of ergosterol gives

A] ergostenol acetate

b] ergosterol acetate

c] nor colanic acid acetate

d] all of these


27. by which process we get oestradiol from oestrone

A] hydrogenation b] hydrolysis

c] A & B both d] none of these


28. oxidation of cortison with CrO3 gives

A] adrenosterone b] androstane

c] A & B both d] none of these


29. molecular formula of cortisone is.....

A] C21H30O2 B] C28H44O

C] C21H28O5 D] C18H22O2


30. the smallest endocyclic valency angle in bicyclo [2,1,1] hexane is

 A] 70° b] 81.2° c] 120° d] 109.28°


31. increase the intensity of the signal is called

A] nuclear overhauser effect

b] protonation effect 

c] magnetic effect

d] None of these

 

32. full form of HMBC

A] heteronuclear molecular bond coherence 

B] heteronuclear molecular bond correlation 

C] heteronuclear multiple bond coherence

D] None of these


33. the protons are directly attached carbon atom the signal of the proton are detected by which detector 

A] HMQC b] HMBC

c] A & B both d] None of these


34. the δ of deshilded proton is .......

A] higher b] lower

c] same d] none of these


35. name of [Eu(FHD)3]

A] europium tris decafluroheptane dione

b] europium tris decafluro heptane 

C] europium Fluro heptane

d] None of these


36. in ipsenol the proton spectrum


displayed in 1H-1H COSY is

A] opposite of F1 andF2

b] bottom side of scale  

c] right of scale 

d] None of these


37. which group’s irradiation is an increased enhancement of H-4 and H-6? 

A] 5- methyl b] 3- methyl

c] A & B both d] none of these


38. which group’s irradiation is increased enhancement only H-4?

A] 5- methyl b] 3- methyl

c] 2- methyl d] None of these


39. which shift reagents are soluble in common NMR solvents?

A] [Eu(DPM)3]2  b] [Eu(FOD)3]

c] [Eu(FHD)3] d] all of these


40. HQF stands for?

A] Hot quantum filtering

b] Higher quantum filtering

c] Hold quantum filtering

d] None of these












5 Comments

Post a Comment

Previous Post Next Post